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A General Synthetic Strategy for the Design of New BODIPY Fluorophores Based on Pyrroles with Polycondensed Aromatic and Metallocene Substituents

Elena Yu. Schmidt, Nadezhda V. Zorina, Marina Yu. Dvorko, Nadezhda I. Protsuk, Kseniya V. Belyaeva, Gilles Clavier, Rachel Méallet-Renault, Thanh T. Vu, Al'bina I. Mikhaleva and Boris A. Trofimov; Chem. Eur. J., 17 (2011), 3069-3073.

BODIPYrrole: A general strategy for the design of novel BODIPY fluorophores based on pyrroles with polycondensed aromatic and metallocene substituents has been developed. The strategy involves the acylation of the condensed substituent and treatment of the acylated derivative (as oxime) with acetylene in MOH/DMSO (M=alkali metal) to give pyrroles that were then used for assembling of the BODIPY fluorophores.

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Publication

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Paru le 14 février 2011

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DOI: 10.1002/chem.201003242