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A Robust Infinite Zirconium Phenolate Building Unit to Enhance the Chemical Stability of Zr MOFs

Mouchaham, G; Cooper, L; Guillou, N; Martineau, C; Elkaim, E; Bourrelly, S; Llewellyn, PL; Allain, C; Clavier, G; Serre, C; Devic, T ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 2015, 54, 13297-13301.

A novel Zr-chain based MOF, namely MIL-163, was designed and successfully synthesized using a bis-1,2,3-trioxobenzene ligand. Endowed with large square-shaped channels of 12 angstrom width, it shows remarkable water uptake (ca. 0.6cm(3)g(-1) at saturating vapor pressure) and a remarkable stability in simulated physiological media, where archetypical Zr carboxylate MOFs readily degrade.

Type :

Publication

Dates :

Paru le 12 octobre 2015

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DOI: 10.1002/anie.201507058