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N-Vinyl Ferrocenophane Pyrrole: Synthesis and Physical and Chemical Properties

O. Galangau, C. Dumas-Verdes, E. Y. Schmidt, B. A. Trofimov and G. Clavier Organometallics, 2011, 30, 23, 6476-6481

A new synthesis of [3]ferrocenophan-1-one has been developed, and a Trofimov reaction has been applied to its ketoxime. The novel subsequent N-vinyl pyrrole ferrocenophane displays reversible electrochemical behavior centered on the ferrocene, without any participation of the pyrrole. Unexpected byproduct was also isolated, in which the α-pyrrolic position is methylated.

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Publication

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Paru le 16 novembre 2011

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DOI: 10.1021/om200839b