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Tetrazine–triphenylamine dyads: Influence of the nature of the linker on their properties

C. Quinton, V. Alain-Rizzo, C. Dumas-Verdes, F. Miomandre and P. Audebert Electrochim. Acta, 2013, in press,

Original new electroactive dyads have been prepared, featuring two different electroactive groups, namely a triphenylamine and a tetrazine, linked through various linkers. We describe here the synthesis, the electrochemical and some photophysical properties of these molecules which are composed of two separate components, one triphenylamine, electron-rich unit, and one tetrazine, electron-poor unit. The electroactivity of both moieties of the molecule is quite apparent in each case and potentials depend upon the type of linker between the groups.

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Publication

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Paru le 4 mars 2013

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doi 10.1016/j.electacta.2013.02.113